I was curious about the carbide content of Rex45 but I can't find any micrographs available for it. I have found the carbide volume listed for it on Knife Steel Nerds, but I'm not sure if he used ThermoCalc or got those figures from Crucible's data sheets. He does have micrographs for Rex76.
This lists Rex45 as having 5.3% M6C and 2.5% MC for a total of 7.8% carbide volume.

This lists Rex76 as having 12% M6C and 5.3% MC for a total of 17.3% carbide volume.

He also has this micrograph and in the book specifies that with ThermoCalc and "point counting" that he estimates 5.5% MC and 12% M6C:

I was very surprised at the amount of difference between Rex45 and Rex76 here, especially because CATRA tests don't seem to place them that far apart.

https://knifesteelnerds.com/2021/05/10/ ... 15-rex-76/
This shows Rex76 was at ~67.5 HRC with ~625 TCC and Rex45 at 66.5 HRC at ~612.5 TCC

If we went by Larrin's KSN blog regression formula estimation:
TCC (mm) = -157 + 15.8*Hardness (Rc) – 17.8*EdgeAngle(°) + 11.2*CrC(%) + 14.6*CrVC(%) + 26.2*MC(%) + 9.5*M6C(%) + 20.9*MN(%) + 19.4*CrN(%)
Rex45: -157 + 15.8*66.5– 17.8*30 + 26.2*2.5 + 9.5*5.3 = 475.55 TCC
Rex76: -157 + 15.8*67.5– 17.8*30 + 26.2*5.3 + 9.5*12 = 628.36 TCC
Although the formula as it is published in his second edition of "Knife Engineering" is a bit different:
TCC (mm) = -157 + 15.8*Hardness (Rc) – 17.8*EdgeAngle(°) + 11.4*CrC(%) + 13.1*CrVC(%) + 25.1*MC(%) + 14.1*M6C(%) + 14.7*VN(%) + 18.4*CrN(%) + 5*M3C(%)
That would change the predictive values to a little bit to...
Rex45: -157 + 15.8*66.5– 17.8*30 + 25.1*2.5 + 14.1*5.3 = 497.8 TCC
Rex76: -157 + 15.8*67.5– 17.8*30 + 25.1*5.3 + 14.1*12 = 661.93 TCC
Not really a significant change, but still shows a pretty wide berth between the predictive results and the actual CATRA data he acquired from testing both.
In the article, Larrin states:
"Somewhat surprisingly Rex 76 was only about 1 Rc harder than Rex 45 despite the higher carbon and cobalt content. And the edge retention is only higher due to the increased hardness and does not seem to have benefitted from the higher carbide content that would result from the higher carbon content. So Rex 76 would primarily be useful for applications where very high hardness is desired."
Given the regression formula estimates, it seems more like Rex45 just scored a lot higher than it should have. I suppose that the difference in heat treatment could have resulted in a much different carbide content than listed? I think that this is likely the case if you consider CPM-M4 in comparison.
CPM-M4 has a pretty similar carbide volume and has about a 575 TCC score at 61 HRC on the chart, whereas the regression formula estimate puts it at 464.4 TCC to 481.6 TCC (-157 + 15.8*61– 17.8*30 + 26.2*5.5 + 9.5*5 vs -157 + 15.8*61– 17.8*30 + 25.1*5.5 + 14.15*5) so clearly real-world CATRA scores and estimates can vary widely--and it seems there's no real-world CATRA data of CPM-M4 at similar hardness to compare against. However the regression formula would land right on 575 HRC if the hardness was bumped up to 68 HRC, which approaches the real-world results (and hardness) of Rex45. If Rex45 merely had a 3% greater MC percentage and .5% M6C percentage the regression formula estimate would track much more closely with its real world CATRA scores, and since there are micrographs for Rex76 showing its carbide content I would lean towards Rex45 being the one with more carbide than actually estimated if we were to trust the formula and adjust the parameters given.
With 17%-20% carbide volumes, the nearest steel in terms of TCC score that also has carbide volume types listed on the chart is CTS-204P at about ~625 TCC when hardened to ~61.5 HRC. So going by the regression formula (-157 + 15.8*61.5 – 17.8*30 + 14.6*17.5 + 26.2*2.5) (using the KSN blog version since I assume the CATRA chart on the site was produced with that) the estimate should be 601.7 TCC, and so the estimate and real-world seem much more closely aligned and seems to point to Rex76 with a ~17.5% carbide volume and CTS-204P with 20% carbide volume both in the 600 - 650 TCC range.
Makes me wonder if maybe the CATRA tests with Rex45 could have been anomalous, or maybe the carbide content for those samples was higher than thought?
Anyway, just wrapping up my weekend geek-out after getting his book for Xmas :)
What do you all think of Rex45 and Rex76 in your use? I'm still thinking about trying to get a Rex76 mule to try out, but so far the Rex45 mule seems to be as rare as hen's teeth on the secondary market. With Crucible shutting down I feel like these will end up even more sought after. Glad to have my Manix 2 before that happened.